.

0 (hodnocen0 x )

BK

First published

New York : Dover Publications, Inc., 1989

xii, 550 stran : ilustrace ; 22 cm

ISBN 0-486-66144-X (brožováno)

Obsahuje bibliografie, bibliografické odkazy a rejstřík

Reprint vydání z roku 1978, Oxford University Press

001462198

Contents // 0. Opening remarks, 1 // 1. A chemist’s view of group theory, 5 // 1-1. Introduction, 5 // 1-2. Symmetry Operations and Molecules, 6 // 1-3. Groups, 10 // 1-4. Point Groups, 14 // 1-5. Classification of Molecules into Point Groups, 29 1-6. Matrix Representation of Symmetry Operations, 35 1-7. Characters and Character Tables, 47 // 1- 8. Decomposition of Reducible Representations and the Direct Product, 55 // Additional Problems, 58 Related Reading, 61 // 2. A skirmish with quantum mechanics, 62 // 2- 1. Introduction, 62 // 2-2. Light, 62 // 2-3. The Postulates of Quantum Mechanics, 68 // 2- 4. Some Simple Illustrations from Quantum Mechanics, 80 // Related Reading, 92 // 3. Vibrational spectroscopy, 93 // 3- 1. Introduction, 93 // 3-2. Infrared and Raman Spectra, 93 // 3-3. Diatomic Molecules, 100 // 3-4. Transitions between Stationary States, 130 // 3-5. The Normal Modes of Vibration of Polyatomic Molecules, 135 // VI // Contents // 3-6. Selection Rules and Polarization, 151 // 3-7. Symmetry Coordinates and Normal Modes, 170 // 3-8. Stretching Mode Analysis, 186 // 3- 9. Assignment of Real Spectra, 190 3-10. The Resonance Raman Effect, 198 3-11. Functional Group Analysis, 201 // Additional Problems, 217 Related Reading, 224 // 4. Molecular orbital theory, 225 // 4- 1. Introduction, 225 // 4-2. Atoms, 225 // 4-3. Photoelectron Spectroscopy, 242 // 4-4. The LCAO Molecular Orbital Method, 245 // 4-5. Diatomic Molecules, 253 // 4-6. Polyatomic Molecules, 267 // 4-7. The

Hiickel Method, 288 // 4- 8. Transition Metal Complexes, 299 // Additional Problems, 302 Related Reading, 306 // 5. Electronic spectroscopy, 307 // 5- 1. Introduction, 307 // 5-2. Another Look at Molecular Vibrations, 307 // 5-3. Basic Notions, 310 // 5-4. Selection Rules, 330 // 5-5. The Electronic Spectra of Some Diatomic Molecules, 343 // 5-6. The Fate of Absorbed Energy, 357 // 5-7. Single Bonds, Double Bonds, and Lone Pairs, 368 // 5-8. Vibronic Analysis, 381 5-9. Transition Metal Complexes, 395 5-10. Concluding Remarks, 411 Additional Problems, 412 Related Reading, 418 // Appendices // A. Character tables, 421 // B. Direct products, 479 // C. Overtones of degenerate vibrations, 492 // D. The shapes of atomic orbitals, 495 // E. Physical constants, 497 // F. Energy conversions, 498 // G. Answers to problems, 499 // Index, 543